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dc.contributor.authorDonohoe, Timothy J.
dc.contributor.authorAce, Karl W.
dc.contributor.authorGuyo, Paul M.
dc.contributor.authorHelliwell, Madeleine
dc.contributor.authorMcKenna, Jeffrey
dc.date.accessioned2012-10-22T15:18:40Z
dc.date.available2012-10-22T15:18:40Z
dc.date.issued2000-02-12
dc.identifier.citationDonohoe T. J. et.al. (200).Reductivealdolreactions on aromatic heterocycles. Tetrahedron Letters.Vol 41(7). • doi.org/10.1016/S0040-4039(99)02224-8en_US
dc.identifier.urihttp://hdl.handle.net/123456789/325
dc.descriptionThe original publication is available at : http://www.sciencedirect.com/science/article/pii/S0040403999022248en_US
dc.description.abstractThe Birch reduction of both pyrroles and furans can be quenched with an aldehyde electrophile, thus constituting a reductivealdolreaction. Although the reaction was not stereoselective, the pyrrolines derived from reduction of pyrroles could be oxidised and then reduced with NaBH4 to provide syn-aldol adducts with high levels of stereoselectivity. The relative stereochemistry of two adducts was proven by X-ray crystallography.en_US
dc.description.sponsorshipPwani Universityen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectBirch reductionen_US
dc.subjectaldolen_US
dc.subjectpyrroleen_US
dc.subjectfuranen_US
dc.titleReductivealdolreactions on aromatic heterocyclesen_US
dc.typeArticleen_US


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