• Login
    View Item 
    •   Repository Home
    • Research Articles
    • Department of Biochemistry and Biotechnology
    • View Item
    •   Repository Home
    • Research Articles
    • Department of Biochemistry and Biotechnology
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Highregioselectivity in electrochemical α-methoxylation of N-protectedcyclicamines

    Thumbnail
    View/Open
    Abstract.pdf (141.4Kb)
    Date
    2008-04
    Author
    Samuel S. Libendi
    Yosuke Demizu
    Yoshihiro Matsumura
    Osamu Onomura
    Metadata
    Show full item record
    Abstract
    N-Protecting groups of α-substituted cyclicamines strongly affected the regioselectivity in electrochemicalmethoxylation of these compounds. Namely, N-acyl derivatives were transformed into α′-methoxylated compounds, while N-cyano derivatives changed into α-methoxylated derivatives. Furthermore, Lewis acid catalyzed nucleophilic substitution of the α-methoxylated compounds protected with cyano group afforded α,α-disubstituted cyclicamines.
    URI
    http://hdl.handle.net/123456789/433
    Collections
    • Department of Biochemistry and Biotechnology

    DSpace software copyright © 2002-2016  DuraSpace
    Contact Us | Send Feedback
    Theme by 
    Atmire NV
     

     

    Browse

    All of PUSpaceCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsThis CollectionBy Issue DateAuthorsTitlesSubjects

    My Account

    LoginRegister

    DSpace software copyright © 2002-2016  DuraSpace
    Contact Us | Send Feedback
    Theme by 
    Atmire NV